上海金畔生物科技有限公司代理日本同仁化学试剂盒全线产品，欢迎访问日本同仁化学dojindo官网了解更多信息。
TFPB
TFPB
- イオン電極用試薬
イオン電極用試薬―アニオン排除剤
-
製品コードT037 TFPB
-
CAS番号79060-88-1
-
化学名Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, sodium salt
-
分子式・分子量C32H12BF24Na=886.2
| 容 量 | メーカー希望 小売価格 |
富士フイルム 和光純薬 |
|---|---|---|
| 100 mg | ￥14,000 | 345-05341 |
| 1 g | ￥77,800 | 349-05344 |
- ご購入方法
- お問い合わせ
マニュアル
-
プロトコル
イオン濃度を電極で測りたい 
技術情報
溶解例
400 mg/10 mL（ジエチルエーテル）
参考文献
1) H. Kobayashi, T. Sonoda, H. Iwamoto and M. Yoshimura, "Tetrakis[3,5-di(F-methyl) phenyl] borate as the First Efficient Negatively Charged Phase Transfer Catalyst. Kinetic Evidences", Chem. Lett., 1981, 579.
2) H. Kobayashi, T. Sonoda and H. Iwamoto, "The First Application of Anion-catalyzed Phase-transfer Catalysis to Friedel-Crafts Alkylation", Chem. Lett., 1982, 1185.
3) Y. Takahashi, N. Yoneda and H. Nagai, "Facile and Highly Selective Synthesis of 2,2-Dialkyl-1,5-Lactones by the Calboxylation of Primary, Tertiary-1,4-Diols with Formic Acid or Copper(I)Carbonyls in the Presence of Concentrated Sulfuric Acid", Chem. Lett., 1982, 1187.
4) H. Iwamoto, M. Yoshimura, T. Sonoda and H. Kobayashi, "Anion-Catalyzed Phase-Transfer Catalysis. I. Application to Diazo-Coupling Reactions", Bull. Chem. Soc. Jpn.,1983, 56, 796.
5) H. Iwamoto, T. Sonoda and H. Kobayashi, "Diazotization of Pentafluoroaniline by Means of Anion-Catalyzed Phase Transfer Catalysis in a Hydrophobic Organic Solvent", J. Fluorine Chem., 1984, 24, 535.
6) H. Nishida, N. Takada, M. Yoshimura, T. Sonoda and H. Kobayashi, "Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate. Highly Lipophilic Stable Anionic Agent for Solvent-extraction of Cations", Bull. Chem. Soc. Jpn., 1984, 57, 2600.
7) Y. Shiraki, K. Onitsuka, K. Takuma, T. Sonoda and H. Kobayashi, "Anion-Catalyzed Phase-Transfer Catalysis. II. Effects of Anionic Tetrakis[3,5-Bis(Trifluoromethyl)Phenyl]Borate Catalyst in Phase-Transfer-Catalyzed Sulfonium Ylide Formation", Bull. Chem. Soc. Jpn., 1985, 58, 3041.
8) N. Ishibashi, T. Imato, G. H. Zhang, Y. Asano, T. Sonoda and H. Kobayashi, "Vitamin B1-Sensitive Poly(vinyl chloride) Membrane Electrode Based on Hydrophobic Tetraphenylborate Cation Exchangers", Anal. Sci., 1988, 4, 527.
9) 市川淳士, 小林宏, 園田高明, "TFPBイオンを用いたアニオン型相間移動触媒反応", 有機合成化学, 1988, 46, 943.
10) G. H. Zhang, T. Imato, Y. Asano, T. Sonoda, H. Kobayashi and N. Ishibashi, "Vitamin B1-Sensitive Poly(vinyl chloride) Membrane Electrode Based on Hydrophobic Tetraphenylborate Derivatives and Their Application", Anal. Chem., 1990, 62, 1644.
11) T. Nagamura, Y. Isoda, K. Sakai and T. Ogawa, "Control of Molecular Orientation of 4,4'-Bipyridinium Cation Radicals in Novel Photochromic Monolayer Assemblies", J. Chem. Soc. Chem. Commun., 1990, 703.
12) T. Nagamura and Y. Isoda, "Novel Photochromic Polymer Films Containing Ion-pair Charge-transfer Complexes of 4,4'-Bipyridinium Ions for Optical Recording", J. Chem. Soc. Chem. Commun., 1991, 72.
13) M. Kira, T. Hino and H. Sakurai, "An NMR Study of the Formation of Silyloxonium Ions by Using Tetrakis[3, 5-Bis(Trifluoromethyl)Phenyl]Borate as Counteranion", J. Am. Chem. Soc., 1992, 114, 6697.
14) T. Katsu and K. Watanabe, "イオン電極法による薬・毒物の定量 (Determination of Drug Substances Using Ion-Selective Electrodes)", Jpn. J. Toxicol. Environ. Health,1996, 42, 453.
取扱条件
| 性状： | 本品は、白色結晶性粉末でエーテルに溶ける。 |
|---|---|
| 純度(滴定，無水物換算)： | 99.0％ 以上 |
| ジエチルエーテル溶状： | 試験適合 |
| 水分： | 4.5～5.5％ |
| IRスペクトル： | 試験適合 |
| PRTR法 | 第１種指定化学物質 |
|---|
